Reasons this ain't happening-
100kwh can't physically fit without a significant leap in battery tech from what they're using in the cars today
Given Tesla has more demand for cars than they have battery supply (and that problem will get much worse with the Y launch) making a change that wouldn't allow for much higher prices, but would reduce # of cars they can build by 25, would be really dumb.
A 25% larger battery would give the 3 a longer range than the S. Larger packs for the S have been long rumored, and the margins on those might actually make sense to do it battery-supply-wise, so 0% chance it'd happen on the 3 before the S anyway.