I might add that I suspect 85kWh is the maximum energy one might get out of tesla's (2012) battery if he charged it to some crazy high voltage, just a bit before exploding, and then discharging it at crazy low current (milliamps) for crazy long time at some predetermined optimal temperature down to crazy low voltage, right into no-return zone, where permanent damage is already done and cells must not be charged anymore.
Just pure experimental maximum, from one extreme to the other.
They then looked at all the variables that affect degradation and performance to arrive at some ~77kWh usable capacity, with different safety margins etc. During production time they learned some additional details, cell chemistry improved a bit so they changed some safety margins and usable capacity for some tiny amount.
There are reports that 90kWh battery contains the same number of same cells as 85kWh battery. It might, or it might not. It may behave differently when pushed to extremes.
Oh, and just don't try to look at capacity through miles of rated range.
That is whole another can of worms and magic and approximation.