All facelift (starting around mid 2016) S-es had 75kWh battery. Some were sold software locked to 60, some to 70. Unlocking the battery to 75kWh is no big deal, it should be already done by the time you pickup the car (even if in the pictures you see 60 or 70 badge), if you bought it as a 75(D). Keep in mind this is for facelift models only. Pre facelift there were smaller batteries sold as well, I don't know about those. Also, this is only about the battery capacity. Uncorking is a different story. Be prepared to talk to reps/advistors who don't know this and when you ask about uncorking, they will say "of course, it's already uncorked to 75kWh".
There's no easy way to tell if it's uncorked before you take delivery. When I went to pick mine up, this was one of the first questions to the boy presenting the car to me. Be prepared to get lied to your face. When you drive it, it should be easy to tell if it takes over 5 seconds to reach 60mph. Most noticeable is between 50 - 60mph. Not uncorked, it's noticeably slower in that range.
My story is still pending. I finally got some communication from my sales advisor today and apparently the firmware push didn't go through. Probably my bad too since the car is not always in wifi range where I park it. Kept it on wifi today but no luck so far. Last thing the guy emailed me was if it didn't work, I'll need to go to a service center. Trouble is, the app won't let me choose that, it just schedules a mobile ranger, which is probably useless in this case (especially if the same guy comes as last time).
I'll stop by the service center tomorrow and try to explain. I don't know how they treat walk-ins.