You're confusing two people in this thread then.
@Benjamin Brooks revived this thread, talking about the builder who ran a 6 gauge aluminum line for car charging, and people were discussing the reasonableness of maybe a 50 or 40 amp circuit for that.
The post you just replied to, though, was
@AmpedRealtor who is running a 100A circuit, supplying 80A. Clearly, you couldn't ever use 6 gauge for that, and he never mentioned wire gauge. He was just talking about how aluminum can be used for part of the wiring run.