Slide 3
· So, there’s a class of materials called the layered chalcogenides, and titanium sulfide is just an example
· We have layers of titanium sandwiched between layers of sulphur, and these sandwiches are bonded together by weak Van der Walls forces
· Into the interlayer spaces, small atoms like lithium can be inserted.
· Graphite is the same, it’s another intercalation compound, so are clays.
· Many, many different materials can accommodate foreign species in between their layers.
· All that was needed was a clever guy to figure out how to make a battery system using an intercalation material.
Slide 4
· That’s where Stan Whittingham comes in.
· He was a scientist at Exxon Research and Development in New Jersey
· He published this paper in 1975, and it was followed with another paper in Science.
· I’ll just read the abstract: it says “The electrochemical reaction of layered titanium disulfide with lithium giving the intercalation compound lithium titanium disulfide is the basis of a new battery system. This reaction occurs very rapidly and in a highly reversible manner at ambient temperatures as a result of structural retention – so when the lithium goes in, the structure’s not changed at all, layers just open up a little bit to accommodate the lithium. Titanium disulfide is one of a new generation of solid cathode materials.
· And here he shows the voltage versus the composition of lithium titanium disulfide for test cells that were made and operated under different conditions.
· This really was the beginning of the lithium battery era.
· I remember, when I was a graduate student here in 1978 to ’82. And in those days, obviously there was no internet, and to get publications from people meant either you had to go find them in the library or somebody would mail you a pre-print. Exxon compiled a blue bound book of all their papers on lithium intercalation compounds, and I remember that book sitting in our lab on our lunch table: that was the bible. These guys did really important work at the beginning: Whittingham, Gamble and Allan J. Jacobson.
Slide 5
Anyway, this is a slide I got from Stan
· He explains how a lithium titanium disulfide battery works.
· You’ve got lithium metal as the negative electrode, and an electrolyte with dissolved lithium ions, and then the titanium sulfide on the other side here
.
· When you connect the electrodes by a wire, lithium atoms dissociate into ions that move through the electrolyte, electrons go through the wire, and then the lithium inserts between the TiS2 layers. And you can just reverse the current with an external power supply and recharge the system.