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Hydrogen vs. Battery

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There is a recent R&D paper about using maganese hydride@1800psi 10.5% wt storage with room temperature absorb and release, leakage may not be too bad compared to 10000psi with pressured hydrogen. The paper does not say if this hydride eats through metal or not.
So, your idea is to take an expensive and inefficient process, and adding a couple of extra steps to make it even more inefficient, and you think that this is a viable future?
 
Hydrogen supply reliability in California remains poor.

B005C1A7-AAD4-4EFC-86C5-7F7E4ED97AE3.png
 
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The myth of the HFC cars will be kept alive by the fossil fuel industry as an alternative to BEVs for as long as they can.
Apart for the mentioned deficiencies, such as low energy efficiency, very expensive re-fueling infrastructure, more complexity in the cars (implies higher maintenance cost), economic disadvantages, there is one more aspect to consider in light of this incident:

Not participating in the discussion, just adding an observation: One of the few hydrogen stations in Norway just blew up.

Kraftig eksplosjon på hydrogenstasjon i Sandvika - fare for flere eksplosjoner

In English:

Google Translate

The fact, that the rear-seat passengers of HFC cars are literally sitting on powerful bombs!
It is not a matter of 'if' but 'when' an accident / car crash will occur that punctures one of those 10,000psi canisters, causing an explosion that will remind everyone of the Hindenburg. That will be the all too familiar end of this second chapter of hydrogen based transportation in human History.
 
The fact, that the rear-seat passengers of HFC cars are literally sitting on powerful bombs!

Well.... I don't know about that... without Oxygen Hydrogen is pretty harmless. The tank itself cannot explode but the hydrogen can leak out and accumulate in the trunk or something. Proper ventilation should prevent it from accumulating to dangerous levels.

Here's an interesting video showing the difference between a H2 fire (100% H2 balloons) and a H2 BOOM (66% H2, 33%O2)

 
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Unless I am mistaken that's just a stupid USA anti-competitive thing isn't it?

In UK a PowerWall can be charged from PV and Off Peak, and be used during power cut (I don't know, but if it is used during power cut presumably it provides power to PV and thus PV generation could be harvested too)

Grid tied solar without storage means when grid goes down, so does solar, probably to isolate the grid while technicians work on it.

Solar + Powerwall(PW) means PW is off grid, i.e. PW2 cannot import from nor export to grid. As u said, this probably is enforced by power company to avoid PW imports at low rates, and exports back at high rates.

The solar in fact can be completely off grid, but most keep the solar grid-tied(e.g. solar capacity not that big, or no battery, or battery not that big, or take advantage of net energy metering NEM).
 
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Solar + Powerwall(PW) means PW is off grid, i.e. PW2 cannot import from nor export to grid. As u said, this probably is enforced by power company to avoid PW imports at low rates, and exports back at high rates.

..... utilities would want that.... the reason rates are low is because there's a supply surplus... charging batteries would help. The reason rates are high is there's a deficit... discharging batteries would help.

There is a lot of hear-say about this;
 
Replying to a lot of posts over several days. Sorry for the long post.

If you are talking direct solar split, then given that the current efficiency is ~15% are you either ignoring the fact your fanciful 36% target is over 2X what's currently possible, or hoping for some technology in the future that may not exist? If the latter, why are you advocating for it now?
Interestingly you inserted a link for the 15% efficiency claim, but neglected to mention that others have reached 19%. https://pubs.acs.org/doi/10.1021/acsenergylett.8b00920
Promising speed of improvement.

If you aren't using solar panels, then you're comparing apples and oranges. The state of the art as far as solar power conversion efficiency goes, is from solar thermal generation stations, which have efficiency around 50%. So even 36% would still be a total joke — 19% approximately doubly so.


About 5.7 million tons of by-product hydrogengas, nearly equivalent to half of annual industry hydrogen consumption, are produced from coke and chlor-alkali processes. Only a small amount of the by-product hydrogen produced is used on-site to produce hydrochloric acid (HCl) in some facilities, while larger portions are either used as process fuel, or sold for town gas. In some instances, it is wasted and evacuated to the air without any utilization,accounting for nearly 3.0 million tons annually.'

So what you have here is an industrial process that releases most of the hydrogen that it produces. Ask yourself this: Given how easy it is to burn hydrogen as fuel, if it were worth the effort, don't you'd think they would be capturing it and producing electricity already? From this, we can infer that the cost of collecting the hydrogen exceeds its value, and that equation will not change with hydrogen cars, because it will still be cheaper to produce new hydrogen with electricity than to capture those waste products. Were that not the case, it would also be worth capturing that hydrogen and turning it into electricity. (Okay, in theory, if it is currently only unprofitable by one or two percent, it might be barely financially viable, but that's noise.)

Besides, 3 million tons of hydrogen isn't much. That's only about 2.7 billion kg. One kg of gas is, I believe, roughly equivalent to a gallon of gas in terms of its ability to move cars, and the U.S. alone used 142.86 billion gallons of gasoline in 2018. Therefore, all the wasted hydrogen in the world would still replace less than 1.9% of U.S. gasoline consumption. Compared with the double-digit efficiency loss resulting from using hydrogen instead of a battery, that bonus 1.9% is lost in the noise. And even if it weren't, you'd still be much better off burning the hydrogen on-site and turning it into electricity.


No, EV charging stations don't need much real estate. They need much less than 1 parking space ...

I assume you mean on top of the one space per vehicle, because otherwise, I'm seriously impressed at your car-stacking charging station. :)


Yep the forum of hydrogen experts are so excited about H2 being dead-end technology that none quotes any latest development in the field, e.g. this international R&D headed by Lancaster University is probably worth throwing in another few billions to explore.

The fossil fuel industry has a vested interest in keeping everyone hooked. Wherever there is money, there are people excited to take the money and do research with it.


Professor Antonelli, Chair in Physical Chemistry at Lancaster University and who has been researching this area for more than 15 years, said: “The cost of manufacturing our material is so low, and the energy density it can store is so much higher than a lithium ion battery, that we could see hydrogen fuel cell systems that cost five times less than lithium ion batteries as well as providing a much longer range – potentially enabling journeys up to around four or five times longer between fill-ups.”

All of this is entirely moot. The limiting factor is the fact that A. the cost of producing the hydrogen cannot realistically ever be less than the cost of producing an equivalent amount of electricity, and B. it would have to be around a third the cost of producing the equivalent amount of electricity to cancel out all the other efficiency losses that occur at every stage along the way when using hydrogen as a fuel source.


Probably good to go back to this diagram:
tony-seba-Hydrogen-vs-EV.jpg


Compression only loses 10% so even if you have a great improvement in compression for storage, it doesn't make much difference in the pathetic overall efficiency of the fuel cell system.

There's no way that power grid distribution results in 10% loss, realistically. The average, at least in the U.S., is only 5%. Besides, why would you include that on the EV side and not on the FCV side? Either the AC goes over the grid or it doesn't, and that's independent of whether you're using it to charge a car or produce hydrogen. So I would argue that the efficiency of the FCVs ought to be 5% lower, and the EVs ~5.55% higher (95/90).


"Hydrogen is one of the few ways of storing that variable energy. Other options include lithium-ion batteries — which power smartphones and electric cars — but they can’t compete with hydrogen in terms of scale. A big hydrogen storage facility in Texas, for instance, can hold about 1,000 times as much electricity as the world’s largest lithium-ion battery complex, in South Australia."

Absolutely. Hydrogen might eventually make sense as bulk storage for the grid. It won't be done with fuel cells, though. They're far too expensive to use at scale. Rather, they'll produce hydrogen in bulk — probably thermally with steam reforming, but possibly by electrolysis — and store it at low density (no compression penalty), then burn it to spin turbines.

That said, the reason it probably won't ever make sense even for grid storage is that pumped water energy storage is 70–87% efficient today, and flywheels can achieve up to 85% efficiency today, whereas steam reforming of hydrogen (currently the most efficient approach) is only 70–85% efficient before you factor in the additional losses from converting it back into electricity, which yields only about 45–51% total efficiency today. So it would need to get half again more efficient to compete in today's economy. That is within the realm of possibility, but pretty unlikely (particularly because any efficiency improvements on the turbine side would also likely improve the efficiency of pumped water energy storage).


If only there were a way to do distributed stationery storage situated near the consumption point...

You mean like the Post-It® notes in the supply closet at work? :D


Now these upcoming rechargeable battery techs improve charge/discharge/energy density/safety, but is there any that can provide 1% discharge after 10 years stored in a cave?

No, including hydrogen fuel cells. All fuel-cell-based cars require a battery, because fuel cells can't ramp up quickly enough, and even if we ignore vampire drain, even if we assume that the battery is a Lithium ion pack, it will still be approximately flat from self-discharge in ten years, by which time the fuel cell will have long since kicked in to bring it back up out of the danger zone to avoid hardware damage. But if you consider a NiMH battery like they use in some FCVs, it will be completely dead within two years from self-discharge, so the fuel cell will have charged the pack at least five times, which is an 8 kWh loss, or ~9% total discharge.

And that's only half the story, if the vehicle happens to have the same level of vampire drain that Tesla cars have, it won't even last as long as the battery in a Tesla, thanks to the higher self-discharge of the NiMH batteries.
 
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..... utilities would want that.... the reason rates are low is because there's a supply surplus... charging batteries would help. The reason rates are high is there's a deficit... discharging batteries would help.

There is a lot of hear-say about this;

In peak rate hours(e.g. today was 100F+ sunny clear afternoon around here) with high demand (e.g. AC), and high supply(e.g. solar at full tilt). The grid is under the most stress at this time. Off grid storage can absorb excess PV outputs and smooth out the load on the grid.
 
NEL (the supplier of the hydrogen filling station that blew up) has closed down the other two stations in Norway and another 8 across Denmark and other countries. (Not sure if US is affected, though it might be.)

There's currently no place in Norway to fill hydrogen on a private vehicle. Though luckily few are affected, as there are only 160 hydrogen cars total in Norway.
 
That means your solar roof does not pump all the excess(e.g, a chunk of 13.5kWh per PW2) back on the grid, instead store it off grid. This reduces the load on the grid in peak hours.

During peak hours export is a good thing. Load is demand. Exporting surplus effectively decreases demand. Storage is grid-tied not 'off-grid'.

NEL (the supplier of the hydrogen filling station that blew up) has closed down the other two stations in Norway and another 8 across Denmark and other countries. (Not sure if US is affected, though it might be.)

There's currently no place in Norway to fill hydrogen on a private vehicle. Though luckily few are affected, as there are only 160 hydrogen cars total in Norway.

Oh the Humanity!!

.... too soon?