That may actually be the best policy - unless your Mom wants to avoid stopping altogether.
Best range is at 25 MPH ... of course it takes you ALL day to get there! Drive at 100 MPH and increased air resistance means you use far more fuel, so have to stop more,and overall it takes you longer.
I believe the sweet-spot is somewhere around 70-75 MPH. You will have to stop, but the time-to-charge, at that average speed, is the same as the driving time - whereas extra time to charge with average speed of 100 MPH is longer than the driving time, and at 25 MPH time-to-charge is much quicker than the driving time. It does depend on arriving at chargers "close to empty", because the battery charges faster when empty, compared to nearly full, and it may be different for S60 than S90, because the bigger batteries add more range, per unit of charging-time.
Starting at 100% SoC and arrive at destination at close to 0% will also help - so on the final leg, once you know you have enough "fuel" to reach your destination (line on the Trip Graph is all green), you can speed up. Just be prepared to slow down if the trip graph starts to show yellow (you will need to show your Mom how to program the supercharger stops into the SatNav, and how to use the Trip Display)