So, what about a workplace with a single 2-headed ChargePoint? Or 2 of them (4 heads)? What's the side-effect? Voltage is <208 V so assuming it is 208Y/120V ?
That would be fine. The issue is that the installing electrician will do his/her best to spread the potential load evenly among phases. But if you're only installing one charger of course you wouldn't be able to split it among three phases. The goal is to keep the demand on all three phases roughly in balance throughout the power grid, which enables generators to run more efficiently, with less wear and tear, and also lets the utility run thinner neutral lines (since neutral just carries the imbalance between phases).
Same as when you put in a generator transfer switch and try to keep the load roughly equal between the two legs of the split phase.