Thank you, very informative. How does one learn about batteries like yourself?
- I've been involved with batteries for over 15 years and have built cell factories in both China and in Michigan (thanks Obama). Your task to figure out which one. Let's just say I worked in France on a joint venture too.
Is it your profession? Are you a scientist?
- yup it's my profession, and I'm an engineer and both process and quality with a degree in chemistry.
A few questions;
- By additive do you mean anode material(graphite) or electrolyte?
- anode. Effectively the Li-ion cell is limited in capacity by the materials in both the anode and cathode. Now while there is work being done on electrolyte, The big advancement is doping the anode with Si.
- electrodes are porous, made of coating a slurry of solvent and active material onto foil. Varying the thickness changes that porosity which in turn can increase or decrease capacity (also charging/ discharging efficiency, and rate)
- Also what is USL spec limit?
- we control the electrode coating by using spec limits USL= upper spec limit. I.e. If you increase the loading, you increase the theoretical capacity of the cell, a jump in mAh.
- By active material loading do you mean cells getting more dense per volume?
- yes, but maybe also a little thinner electrode with higher loading and lower porosity means longer wound length of components in the cell.
- How do you think they got around Si expanding and harming the cell when charged vs. discharged?
- Do you think they were not sure how it would affect the pack so they limited Supercharger capability for 90 packs, making them slower than 85 packs upon delivery and after enough data collected they updated it so 90's supercharge way faster now. (remember news from a few weeks ago?)
- how to conquer the Si swelling and cracking issue in he electrode due to swelling. Honestly I have no idea. Amprius is a company working on pure Si anodes. I'm waiting for the day this is perfected and battery capacity makes a huge leap forward.
But a little Si doesn't hurt so much when bound inside a carbon matrix. Remember the cell "jelly roll" is tightly wound.
However for the 100kWh pack discussion might I add news outlets say cells are the same. Addition of Si to the anode(thanks for correcting) was only on switch from 85 to 90 packs. As far as I interpret that made the cells go from 3100mAh to 3300mAh. So this was pack level innovation more than cell level. If the new pack was the same architecture but with more addition of Si resulting in 3700mAh cells, it would've been an amazing advancement.
However I'm fairly confident that they'll do amazing feats with the chemistry of 21-70. Current 18650's volume will increase 40%. With the current 3300mAh chemistry that takes them up to 4600mAh. With further advancements in cell chemistry they probably could achive 5Ah cells or maybe more.
- totally right and a great time to be involved in battery development.