So I had a bit more time to play around with the frequency. It looks like as the powerwalls approach a full charge it will start slowly increasing the frequency until the inverters shut off. In my case when the powerwalls had been at 98% for a little while it would bump the frequency up to about 60.2 or 60.3 (my kill-a-watt kept fluctuating between the two) and that was enough to shut off the inverters. The house would run on the powerwalls until they got down to 97%, then the frequency would drop back down to 60. Obviously nothing in my house had issues with the 60.2 or 60.3 frequency.
So it looked like the powerwalls had to be charged to 100% for the max frequency adjustment, so I went ahead and connected myself back to the grid. My powerwalls were in backup mode, so it ran the house on the grid and put all the solar into the powerwalls. For some reason it only charged the powerwalls to 99%, then they stopped charging and it started sending excess solar back to the grid, which I didn’t want to do, so I went back off grid again. I’m not sure if they would have gotten up to 100% eventually or not. But in any case, as soon as I went off grid the inverters stopped and the frequency was up to 62.3. I certainly couldn’t check everything, but I checked some of my lights as well as my UPS, my microwave and my heat pump and nothing seemed to have a problem with the 62.3 frequency. As the powerwalls drained the frequency slowly lowered until it got back to 60 when the powerwalls were at 97%.
So, after all that, it seems like the 62.5 frequency that they set me at will work fine for me.