I know this isn't specific to Powerwall 2.0... but do power companies let you store their energy at super low peak rate and export back to grid at on peak rate when you are under the TOU plans?
Outie, Strider is right about it depends on utility. But buying back power is a function of NET Metering, not TOU. These are two separate programs. If you are a NET Metering customer, you have an agreement with the utility to generate power and sell back to the utility pushing it to the grid. But as a TOU customer, you just buy it and depending on time of day, you pay different rates per kw. You could be both a NET Metering and a TOU customer or just NET Metering or just a TOU customer.
For instance, here in Hawaii, we have more than one NET Metering arrangement. Some of us are fortunate to sell the power we generate back to the utility at the same rate we buy it from them at night. But just before they closed the NET Metering program to new customers (Oct '15), they also changed it. When they changed it, the utility lower the buy back rate from $ .26 per kw to $ .14-.15 per kw. This means someone wanting to add solar during that time had to increase the quantity of solar by about 40% to break even at the same $$ as those of us that got in early.
TOU is simply different rates for each kw depending on when/what time of day you used it/buy it. Of course its not automatic, you had to sign up to a TOU plan. Here the utility announced a pilot program to access 5,000 customers to a new TOU rate plan. In less than a week, 5,000 customer had signed up and max'd the available slots.