In a
conductive material, the moving charged particles which constitute the electric current are called
charge carriers. In metals, which make up the wires and other conductors in most
electrical circuits, the positively charged
atomic nuclei are held in a fixed position, and the negatively charged
electrons are free to move, carrying their charge from one place to another. In other materials, notably the
semiconductors, the charge carriers can be positive
or negative, depending on the dopant used. Positive and negative charge carriers may even be present at the same time, as happens in an
electrochemical cell.
A flow of positive charges gives the same electric current, and has the same effect in a circuit, as an equal flow of negative charges in the opposite direction. Since current can be the flow of either positive or negative charges, or both, a convention is needed for the direction of current that is independent of the type of
charge carriers. The direction of
conventional current is arbitrarily defined as the same direction as positive charges flow.
The consequence of this convention is that electrons, the charge carriers in metal wires and most other parts of electric circuits, flow in the opposite direction of conventional current flow in an electrical circuit.