You can precondition anytime using the Tesla app, don't need to be plugged in to precondition. The standard preconditioning warms the passenger cabin; also defrosts the windows and cameras and can turn on the front seat heaters and steering wheel heater. The standard preconditioning will also warm the battery if needed but not nearly warm enough for optimal Supercharging. (Preconditioning for Supercharging, as you noted, happens when you enter the Supercharger as the destination in the Tesla Model Y Navigation system and you are actively driving. (The Tesla Model Y won't precondition for Supercharging while parked so being plugged in is not an option. (This would be redundant since you would already be plugged in and able to charge or Supercharge.)