I doubt there is much application for using it for a super charger. I suspect that there is some communication that goes through the supercharger cable that would not pass through the extension. And like someone mentioned it might sense something is very wrong with the huge voltage drop.
The real danger is using it in a wall connector. The cord on a wall connector is way beefier than that extension. Not sure if the wall connector would detect an issue.
Like others said I’d never buy anything like that. I’m sure it’s Chinese crap that has no regulation or certification. It probably would work at 32 A and no more. Still wouldn’t touch it.
I agree there's little application for using it at a supercharger, but I can think of a few. Model X towing a trailer, for example. You can't pull into the supercharger stall without disconnecting the trailer, so I can easily see someone pulling up to the supercharger stations and using the extension cord because they don't want to disconnect the trailer.
Making it so that J1772 protocol would go through the extension but not SuperCharger protocol would involve a highly sophisticated microprocessor-controlled circuit that would have to decode the protocol. I virtually guarantee that is not implemented in this cable as it would drastically raise the cost.
The voltage drop on the cable
might indicate enough to the car that the charging session should be stopped, but there's no guarantee of that. In fact, the car might not notice. As the voltage drop across the cable increases with the increasing current, the voltage at the car drops. The car would actually tell the supercharger to increase the voltage further so that the desired charge rate would be maintained. Only if the supercharger and the car communicated and told each other what the voltage was on their own end would the large voltage drop be recognized and I'm not sure if the supercharger protocol includes such cross-checks.
You're right that using it on a wall connector is just as or more dangerous. J1772 protocol is used, so even a microprocessor-controlled circuit couldn't stop it unless it was watching the commanded current value and shut it down if it's too much. Even then, such a thing could never get certified by UL or NEMA since active protection is required for the overcurrent condition.