When the grid is down, the Powerwalls will maintain 60Hz until it needs to curtail generation. Curtailment is always signaled by increasing the frequency. How high it increases is a configurable parameter that only Tesla can modify. It will also ramp up the frequency relatively slowly and if your solar inverters are configured to respond to it, they will proportionally reduce their output. However, some grids require "ride-through" programming which prevents the inverters from gracefully curtailing like this. In that case, the inverters have a hard limit on frequency and will abruptly halt their output when that threshold is reached. That value could be anywhere between 60.5Hz and 62.5Hz. There are other special conditions when Tesla doesn't want the Powerwalls to take a charge off-grid, so it will raise the frequency when those conditions, like low battery temperature, occur.