Even if it's not a true 100% but 100% is say 90%, charging to 90% every day is still a lot worse on overall lifetime than say charging to 80%.
There is no current way to charge the powerwall like many charge the car. It will charge to 100% in the app if there is enough solar to do so.
That's true but Tesla still says don't charge past 80% daily unless you need it. If you need it, do it but they are clear that the higher charge, the more it will effect lifetime. And it most certainly has been demonstrated that depth of charge for x number of kwh matters but I'm sure Tesla is balancing between the most optimal perfect use pattern and convenience for the consumer.
Since this is not any of the tesla car sections, I am not going to get into the "what tesla says or doesnt say" regarding charging to 80% for the cars. I will just say that there isnt any way that I am aware of to do what you are asking with the powerwall. In fact, tesla has designed the app so that if you put it in backup only the powerwalls float between 97 and 100% for days / months on end, and if you use other modes the powerwalls will charge up to 100% visual in the app when there is power to do so.
TL ; DR, no way to charge to 80% using the tesla controls that I am aware of, although I do believe I remember reading someone here had scripted / automated something for themselves to do something similar to what you are asking for.
I think it was
@JayClark (who I am tagging here to see if I am remembering that correctly or not.. sorry if I am mis remembering this)
I personally think charging to 100% for the powerwalls is a non issue, since tesla allows people to put them in backup only mode and run them that way for what would be years, with no change in warranty.