There is a discussion here. NEC bumped up the receptacle ratings to 125/250V in anticipation for future increases (just like when 110/220V moved to 120/240V) but that doesn't mean the power companies have moved to it yet.
The title says everything, you know so yeah. Why do certain wiring devices have the ratings 125v, 250v.
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For example, my recent charge session was still 236V and my outlet is literally on a sub panel on the other side of the wall where my main panel and service entrance is. I'm pretty sure most people if they take a multimeter and measure the voltage at their residential service entrance, it'll be around 240V, not 250V.