You sure about that? It looks like for 50°C/9.3 months, the local maximum in degradation around 80% is gone, and it's monotonically increasing after 70%. Who knows what happens after say 12 months or 18 months, or at 25°C for 50 months, etc.?
That’s not sure in as very sure, but reading the research and what drives calendar aging and how it happens, it would be a fair guess that it will be the accumulated amount of degradation processes that set the rate of degradation.
Im not currently at home, so my biblio of reports isnt available. Didnt find the correct report for references…but:
At low SOC we have mainly anodic side reactions.
Consequently, solely anodic side reactions are the predominant aging mechanism at low SoC. These side reactions, which are related to electrolyte reduction and SEI growth, are known to cause right-shifts of the discharging endpoints and this agrees well with the observed transformations of the charging curves.
At high SOC we have also cathodic side reactions.
Side reactions at very high SoC.—In addition to the slippage of the discharging end point, Figures 10d–10f show the slippage of the charging end point. It is moderate or small for storage SoCs up to 80%. For storage at 100% SoC, however, increased shifts of the charging endpoints are observed at all temperatures. This indicates aggravating cathodic side reactions. As described above, there are also larger shifts of the discharging endpoints for storage at 100% SoC. This supports the assumption of coupled side reactions, e.g., from transition metal dissolution at the cathode and a reduction of the dissolved transition metal ions at the anode.
If we mainly stay low we started ”burning the high side”, so the cathodic reactions havent happened.
If we only use high SOC for short times it will take very long time to accumulate the 6 months when we still have lower calendar aging at 100% than at 80-90%.
My own tests with 35 pieces of 2170 support this.
There is still higher degradation at 80% than at 100%, and these cells have been at 100% for 3months (at 10C) as the first test.
The cells are now 1 years and 4 mounths since I did get them. I have no data om the manufacturing date.
Last checkup was in february, and the latest three month calendar aging was higher on the once at 80% then the onces at 100%.
For 2170, this test show that this continues at even one year. We do not know the brand of these cells, but there isnt many 2170 NCA manufacturers.