The static that builds up on her will include her hair. Everyhithing (hair and body) has the same charge, so the hair strands are being repelled (from her body and from each other).
This is exactly the same as when I demonstrate the VdG generator at school. There is nothing attracting, it is all repelling.
Apart from the cars I’ve owned with leather seats, all my other cars have given me static to a greater/lesser degree. But it is generally the combination of materials, duration of the journey and the level of humidity in the air that determines the extent (between the occasional tingling feeling to seeing a bright spark at night)