Are you sure AC was not on remotely? My experience is, when you turn it on remotely, it turns on, then when you open the door, the AC reverts to the setting it was when you got out. Said another way, if you turned it on, remotely, are you sure it didnt come on and cool the car, then when you got back to the car it simply turned off because thats how it was when you left it?
I am not 100% on this, but seem to remember it working like that. You could test it, by turning it off like you did, waiting a bit for the car to get warm to hot inside of it, then turn on the AC remotely and let it run for 15 minutes or so, go to the car, and see if its cool inside.