What is your goal in doing this? I don't feel like playing in the safety margin of the load calculation is a great idea and as you mentioned, looking at the hourly stat on a website is extremely crude.
The fact is that having a hot tub on a 100A main breaker eats up all your headroom. Google for "hot tub 100a breaker" and you will see a lot of people feel like having a hot tub on 100A service is pretty much on the edge. Now add in the fact that you have an electric dryer. And now you want to further add continuous EV charging on top of that.
Let's say 50A for the hot tub and 30A for the dryer. That leaves just 20A for the rest of the house. A hair dryer or microwave would probably blow you past the limit. How realistic is it to add EV charging in on top of that?
I'm thinking this is obviously a no go. Use a splitvolt or upgrade to 200A service.