Part of the battery is reserved to prevent complete discharge which would likely destroy the battery. You have no access to that part of the battery. You will never get the nominal battery rating for your use. If the battery is at 100% regen is not possible and you better be ready with the brakes to stop the car.
Isn't that the reason why there is only 72.6 Kwh usable? Or am I understanding it wrong?
That's how I understand it as well...