I believe you can still zero toe with the factory eccentric bolt, but it is almost impossible to do without a rack. Conversely, it is pretty easy to re-align toe using toe arms given how much easier and more predictable it is to use turnbuckles. Specifically, each 0.1 degree of toe is about 1/6 of a turn on the turnbuckles (one side of the hex); you can measure toe with simple tools while the car is on the ground, write down the required adjustment, pull the wheels, and adjust the turnbuckles by the required amounts. I can’t think of a way to reliably and precisely adjust eccentric bolts using typical measuring tools available to even a pretty advanced home mechanic.
Bottom line: if you are okay aligning periodically in a professional rack, you can likely get away with just camber arms. If you want to be able to adjust toe on your own from time to time (I.e. after adjusting camber, adjusting ride height, or just correcting for settling), you’ll probably want the toe arms as well.