According to the owner's manual, when you double-click the Defrost button, you get maximum fan speed and maximum heating, which implies that the temperature control setting will no longer apply. Which supports someone's earlier statement that a single click leaves the temperature setting as it was but directs air to the windscreen. By the way, that function times out and shuts off after a while.
If you want to direct air to the windshield and leave it like that, you can do so with the manual controls by clicking on the fan button and setting the air flow to include the windshield. This is useful in winter if you want to be able to preheat the car AND include the windshield. if you leave the airflow set to the windshield (with or without any other airflow settings), it will remain like that until you set it back. I do this when I expect snow or ice overnight, to facilitate clearing the windshield while preheating. If you leave it in AUTO and preheat with the phone app, you rely on the car to decide whether or not to run the defroster (sometimes it does, but it may shut off too soon).