Aside from the availability of the stock, I think the biggest differences between the PwrCell and Powerwalls are simply the PwrCell being DC coupled instead of AC coupled. Some folks like this configuration better because it's more efficient to just turn the DC coming from your solar into DC that gets pushed into your battery. All energy coming from solar and from the batteries has to pass through the Generac inverter.
However, this bottleneck through the Generac inverter kind of becomes the downside of Generac systems. Since their largest inverter is capped at 11.4 kW, it tops off at 50A continuous. This simply isn't enough to run a whole home backup since I don't believe these systems are stackable. As such, Generac systems almost always have a critical loads mini-grid of generation sources and backup.
My understanding (although I'll be damned if I could find a local installer who knew what I was talking about) is that the Generac Gateway is smart enough to meter loads upstream of the backup loads panel so the system can be instructed to export energy from the PwrCell upstream and
help energize loads with stored clean energy when the
utility is operational. But of course it is limited to a 50A max export.
Because of this wonkiness, one licensed/certified whatever Generac local installer I spoke with said he wouldn't install Generac that way since he typically puts in Generac like any other gas generator or critical loads backup. The Generac system would not see the upstream loads nor would it care to do anything except manage the backed up loads.
Another local installer said what I described with upstream sensing was do-able because the Generac system supports the CTs necessary to meter the load. But he also said he's never seen a customer ask for this. As such, I just don't think Generac is as ready for time of use balancing across the entire home.
Contrast that with Tesla Powerwalls where people like
@Vines seem to be able to design highly flexible systems with Tesla's systems that provide partial backup along with whole home energy management when the utility is online.
Also, both battery types are lithium LMC so I think from a chemistry standpoint they're similar. But of course people can deliberate who makes better batteries in through the complex manufacturing processes