You mean watt-hours/mile or kWh/mile? (Many (most?) non-Teslas use the inverse: miles/kWh.) The rest of your unit usage was correct.
Since nobody's stepped up (it was extremely late last night for me and I had things to do today), I'll take a stab at some numbers.
E-1 schedule is at page 1 of
https://www.pge.com/tariffs/assets/pdf/tariffbook/ELEC_SCHEDS_E-1.pdf.
From the table at
Baseline Allowance, E-1 basic electric (applicable for the OP) baseline is currently for area X 10.3 kWh/day for "summer" and 10.5 kWh/day for "winter". So, for a 30 day billing month, his baseline is 309 kWh/month for "summer" and 315 kWh/month for "winter".
For every one of his months, he's hitting tier 2 (101% to 400%) of baseline that currently costs 28.92 cents/kWh.
Let's assume he only achieves 3 miles/kWh including charging loses and the various vampire/phantom losses. We could use a range of 3 to 4 miles/kWh. It will depend on his habits (how fast he drives, heater usage, usage of stuff like sentry mode, cabin overheat protection, etc.). So, 80 miles * 3 days/week = 240 miles each week. Let's assume 4 weeks, so 960 miles/month.
960 miles at 3 miles/kWh --> 320 kWh.
For each kWh within tier 2, he'll currently pay $0.28920/kWh. That * 320 kWh = $92.544, which is how much his bill would go up by, using these assumptions. That comes out to about 9.64 cents/mile.
The real killer is if he hits tier 3 (400% of baseline). Each kWh beyond the 400% mark costs 50.667 cents. If one achieves 3 miles/kWh, then it'd be 16.889 cents/mile.
I don't know what current Supercharger pricing is in his area, but I suspect it might be cheaper to SC than to pay 50.667 cents/kWh.
If his other car is an Audi R8 (mentioned in another post of his), yes. That's not a fuel miser.
If he's driving a fuel efficient car, no. I had an 06 Prius for over 13 years. If I only achieved 40 mpg (easy with my commute) and gas were $4/gal (it's not that high now), that's only 10 cents/mile. 9.64 vs. 10 isn't a huge savings. A more realistic 44 mpg of what I'd get in the past w/o too many short drives and say $3.30/gal --> 7.5 cents/mile.
And, if I got pushed into tier 3, it'd be much cheaper to but gas in my former Prius than to pay Pacific Gouge & Extort.
Fortunately, I have free L2 charging at work and have some free (albeit busy) L2 charging options near home.
PG&E has numerous TOU plans but they each have different time bands and rates for peak, partial peak and off-peak. It's very difficult to calculate and the plan may/may not work for the OP (e.g. energy usage at home might be high during expensive times, negating off-peak savings).