So there will be a small number of sites which are AC only. (I had hoped they'd be 25kW DC but this appears to not be the case).
They are:
Berri, Yalata, Border Village, Glendambo, Marla and Yunta.
Berri isn't an issue as it already has an NRMA unit and nearby towns are getting fast chargers under this plan.
The other five, if excluded, give the following gaps between towns (I've used the closest sites over the border in some cases, which is a big assumption since Eucla and Erldunda currently have no plans.)
Skipping Glendambo and Yunta are probably OK assuming a long range EV.
Skipping Marla would be stretching it for all but the longest range vehicles.
Skipping both Yalata and Border Village are no-goes.
Devils Advocate: Crossing the Nullarbor is a multi-day trip no matter where the chargers are, so a trip could *probably* be done without an issue.. but you would be working around the charging station locations, and the point of a fast charging network is that you don't need to do that any more.