It actually makes a bigger difference than I thought. In NY, the daily temperature can vary by 30+ degrees a day. If it's been hot for a few days and I have my tires inflated to 42 (idle temp pressure) and the next day it could be in the 60s. I've seen the pressure then drop to 37 or so and then the tire pressure light turns on in the morning but turns off after a short drive.
Um.
Basic chemistry: The Ideal Gas Equation is Pressure * Volume = n * R * T, where:
n is the number of moles of the gas.
R is a fudge factor.
T is the temperature in Kelvin.
The "R" value depends upon what units one is using: Pascals of pressure, volume in liters, and so on. R is pretty much fixed until one gets crazy, where, "crazy" means any of the following:
1. One is playing around where the gases are liquefying, either due to extreme pressure or ridiculous cold.
2. The gas is ionizing, usually due to ridiculously high temperatures.
Neither of the above is true at any temperature we tend to run cars around in.
Generally, if one solves for Pressure, one gets this: P = (n*R)*T/V.
Hokay. Fill the tire up with Nitrogen, standard air, or, I dunno, Helium. Or Krypton. (That is a gas, not an anti-Superman thing.) As it happens, for any gas, one mole of that gas occupies 22.4 l at 0 C. So, one might have different amounts of
mass of air in the tire, but the number of molecules will be the same.
So, one fills up a tire when it's, say, 35C out there, to a set pressure above ambient, say, 52 psi. Volume is fixed. "n" is fixed. "R" is fixed. T is not fixed and can go up and down. And, sure and begorrah, the pressure will go up and down with the temperature. So:
delta-P = (n*R/V)(delta-T).
Period. I strongly suspect that changes seen by a single PSI or so is simply measurement error.
Now, if one wants to argue that dry Nitrogen doesn't have any water dissolved in it, which normal air at some compressor will, then, sure. I suppose a bit of water could cause corrosion. Or if one filled up one's tires on a really humid day when it's 45C out, then drove straight to somewhere where it was below freezing (and didn't back-fill more air because, natch, the tire pressure would have dropped), there might be some condensation and/or ice forming in there. Betcha airliners have issues like that, given that flying around at 40,000 feet gets one well below freezing. (And probably explains why their tires get filled with Nitrogen.) And.. I made a joke about the Helium, but Helium (or Hydrogen) are teensy little molecules that leak through things relatively easily.
I just looked it up: Nitrogen (N2) molecules are 3.15 A in diameter, Oxygen (O2) is 2.98 A; so I guess Nitrogen will leak out slightly slower. Krypton has a diameter of 4 A or so, so would be even better, but more expense.
I think this whole business with Nitrogen is the same thing as gold-plated wires used by the maniac audiophiles: Doesn't do anything for anybody, but it sure is more expensive.