When charging at the same voltage, there's very little difference in charging efficiency. If anything, it's a little less efficient at 80 amps because the pumps and fans are sometimes going:
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I have hundreds of charging sessions logged from 20 amps to 80 amps and unless the cooling system turns on, it's always right around 90%.
Some might confuse longer charging with efficiency since that's often associated with lower voltage. Charging at 110v *IS* way less efficient because the inverter's overhead to step it up to 400v is far higher than stepping up from 245 volts.
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Over 50+ charging sessions at work on 110v, my average efficiency is about 71%.