No. When talking about old streetlights, it's high voltage as in several kilovolts. A single transformer pumps up the voltage for a whole string of streetlamps in series. The only reason that they don't all go out when one bulb burns out is that they're designed to fuse the circuit closed at a bulb if that bulb burns out. Individual streetlights, obviously, cannot be turned on or off in this arrangement, and there is, obviously, no power to them except when the lights are on.
This is the older design for streetlights, but it's still in use in places. Parallel lighting is predominant in modern systems, although series is still dominant in airfield uses. Even for modern parallel streetlight systems running on mains power, though, there's no guarantee that the circuits will be live during the day, and the wiring won't be rated for EV charging currents.