I was also reading that if you don't charge regularly to 3.92V/cell, you can have SEI buildup on the anode. So perhaps charging to 60% is the best option?
BU meta description needed...
batteryuniversity.com
I wouldn’t guess the article really says
“ if you don't charge regularly to 3.92V/cell, you can have SEI buildup on the anode.”
I just scanned it briefly, and couldn't see it.
Most certain they mean to stay below 3.92V. Not that you gain anything to actually go up there if you can stay below.
SEI is the main calendar aging degradation factor. There is a (thin) SEI layer formed the first time a lithium ion battery is charged, which is fine/ok( we really cannot be without it, as we need to charge the battery).
SEI Grows from time x SOC x temp.
The SEI can also crack, creating openings which causes a new layer which increase the thickness further.
The lower the SOC, the less is the SEI growth. The lower the temp, the lower is the SEI growth. The longer the time, the thicker the layer gets.
I have not seen
any research report finding the need to charge to 3.92V. I did read
a lot of research. Actually more or less anyone accessible on the net, including quite a few that needs the authors approval to be downloaded.
I will bail out from a long post by linking to one of the easiest read reports that actually covers most of the parts that can be of interrest for a EV owner:
Good research report
I chosed this report as it covers all the aspects we discussed so far. There are reports that go more into the deep but they mostly look into only one thing(like calendar aging only).
Its not too long, but if you like to shorten the time look at this:
1.4 Contributions
2.2.1 Calendar aging and cyclic aging
5.2.1 Calendar aging tests (including graph)
5.2.2 Cyclic aging tests (including graphs page 51 and 52)
5.3.1 Aging in small SOC intervalls(including graphs page 59)
The battery cells in the research is NMC/LCO mixed cells, but the principles is the same for Tesla/Panasonic. All graphs referenced above shows the principle that is also valud for these( exact numbers/cycles is not the same, but the effect of calendar aging and cyclic aging is).
Important: FCE= Full Cycles Equivalent. This means that for one FCE there is 10 cycles with 10% DoD, or 2 with 50% DoD.
1000 FCE with 10% DoD is actually 10.000 small cycles.
Comments to the ‘should read pages’:
5.2.1: Low SOC is king, and High temp with high SOC is not good. Time = wear.
5.2.2: Small DoD(cycles) at low SOC= the batteries lives forewer!
0-90% gives some 3000 FCE
60-70% gives about 5000
40-50% seem to flat out at 85% capacity and live long.
10-20% stays above 90% capacity forewer!
5.3.1 Aging dependent of SOC
Its very clear that the lower the cycle is in SOC, the less the wear.