Back to the subject, car and aircraft makers would be very happy to find a hard, scratch resistant, light, and transparent material to make windows out of. Aircraft use plexiglass because light weight is most important. Plexiglass was one of the first plastics and was in widespread use by WW II. It is as clear as glass and has the advantage of being much lighter than glass, but it is much softer than glass and can still shatter. Glass is very heavy, but it's the best material for cars which are exposed to more debris than aircraft and where weight is not as serious a problem. It's a tough problem, despite the obvious rewards to someone who can come up with a better material, nobody has in 100 years or so of trying.