I'd be cautious about this. There is plenty of cycle life data on lithium cells. While it's true that calendar aging can be minimised by not leaving batteries at a high SoC for long, cycle life is still adversely impacted by charging to a high capacity (termination voltage). While the occasional 100% won't make a difference and will keep the BMS up to date, I'd be wary about doing it on the regular.TBH, NCA is happy to be charged to 100% as long as you're going to be using it. What it doesn't like, which is to be left at close to 100% and just sitting there in the garage.
As a side note, when you charge to close to 100% you'll use your brake pads as the charge level is too high to do regen.