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100D or 105D speculation

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I drove the battery down to 20% then charged on L2 to 90%, recording the data given below using teslafi.
Charging capacity = 68.76 kWh/(249.59 mi/369 mi) = 101.7 kWh.

I don’t find this particular partial charging test to be anywhere near rigorous or scientific enough to support your claims that there was a quiet chemistry change that resulted in an unpublished capacity increase.

There are way too many variables that make this a dubious claim at best.
 
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I have a 100 pack from mid-2020 in my personal S. Its usable capacity is 97 kWh, well inside the range of known 100 packs. A vehicle I recently saw from 2021 has the same pack part number. Seems unlikely they would change chemistry but keep the part number.
 
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Here is more charging capacity data, the charge capacity decreases as the battery wears and range drops, as you can see below.
Energy (kWh)Rated MilesRated 100% rangeCapacity (kWh)
49.15180.85369100.3
68.76249.59369101.7
72.86267.8835997.6
86.05315.9735997.8
79.41288.6235998.8
77.61285.1235997.7
62.97233.2235896.7