800V is a whole different ball game. Different wire insulation requirements, DC arc arresting, etc. Good luck finding a reasonably priced high current 800V DC contactor.
An advantage would be that the higher voltage would allow higher power at lower currents, if the pack could handle it. But voltage alone doesn't really tell us a whole lot.
Plus, I don't believe any existing charging standard supports 800VDC. So, I'm thinking someone typod this, honestly. It's likely be way more trouble than it's worth to go above ~500V.
I don't think it's a typo. It's all over their website and they even wrote it on the side of the car.
Of course, whether it's mass producible at reasonable cost is a wholly different story.
What I find interesting is that they are claiming a quick charging time that's about half what Audi is claiming for the Q6. Hard to imagine that the cars would have radically different technology, given that they are both part of VW now, but I suppose anything is possible.