I have to correct a few things in this...
6 AWG copper, THHN, 90 deg C, is good up to 75 amps. The 6 AWG rated for 105 deg C in the HPWC is good up to 85 amps.
The install guide for the HPWC says 3 AWG for the power conductors, and 6 AWG is sufficient for ground.
6-3 would not burn down the house at 100 amps, although it would get quite warm.
And to the poster, get yourself a new electrician.
Thank you for the clarifications FlasherZ!