I was asked by a friend for further explanation on the volts bit, as he was sure from his school days that volts in a cell do go up and down. But I was saying they don’t. He is correct. Yes they do. The volts I am talking about, in relation to the degradation point, is an upper limit rather than the amount of charge a cell stores.
There are two separate issues here. The amount of volts that the cell is designed to accept, ie the range of charge. And the amount of charge a cell is actually holding at any one time. They are related but different, but it’s easy to see why there might be confusion.
First one: the Volts each cell is designed to accept. A battery is designed to accept a range of energy, ie the range between empty and full. If it takes on too much, or loses too much, it damages the cell. So BMS software sets an upper and lower level. There is a maximum figure (Vmax) and a minimum figure (Vmin). Although it’s a poor example, think of it like a fuel tank. When all the cells are at Vmax, the total charge (in a 70 kWh battery) equals 70 kWhs. And when it’s at Vmin, the available charge is 0 kWhs. But if you change the Vmax to a lower figure, (which is what Tesla appear to have done) then the tank is suddenly smaller. So it’s a bit like changing a 70 gallon tank for a 60 gallon tank. Then when the customer complains that the car won’t go as far, the maker says, nothing is wrong, your fuel tank is healthy, it’s just normal wear and tear from driving. You are still getting the same range as other cars of your age and mileage. Erm no. It’s because the size of the fuel tank has been changed. And just like Volt Capping, however much the engine wears out, the fuel tank still stays the same size. This is why volt capping isn’t degradation. Volt capping is changing the size of the fuel tank. Degradation, however severe, will not change Vmax. That can only be done artificially.
Second one: How much the cell holds, sometimes referred to as Open Circuit Voltage, is entirely dependant on the State of Charge. At full SoC it should hold 4.2V. At low SoC it may only hold 3.1V or so. In a badly degraded battery, whilst it will still try to charge up to 4.2V, it may not manage. But the 4.2V limit will still be there. Which is why in older EVs, the max charge reduces to a figure below 100%.
So, yes, the voltage in an individual cell certainly does go up and down. And degradation will have an effect on that. Voltage capping is just changing the size of the fuel tank. Reducing the size of the fuel tank (battery) reduces the battery's available capacity, which in turn produces less range. But this sudden loss has nothing to do with degradation. It’s to do with the sudden reduction in the size of the fuel tank.
Hope that helps.
@Ferrycraigs, thanks for your diligence and yet another clarification. And my sincere apologies in advance for going a bit off topic, even though helpful, but did you know this:
Yes, Flat-Earthers Really Do Exist