Alchemist42
Member
The main disadvantage of NCA is that it degrades directly to a non-conducting rocksalt layer, while NCM degrades to a conducting spinel first. And on thermal runaway its the first to release oxygen.
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The advantage is that its cheaper, as long as you can handle its process from base material to cell.
Once your battery reaches 200°C, I suspect you have bigger things to worry about than degradation. Point taken, though, some of the recent fires might not have happened with NMC chemistry. Then again, there was a recent case with a Hyundai Kona EV spontaneously bursting into flames as well.
The problem with the cathode NaCl structure is if course present in NCA, but this is a slow process that can be drawn out over many thousands of cycles, especially when performing shallow cycling. I suspect however that the reason for the whole thread does have relatively little to do with the cathode.